While the demo template is extensively commented, any additional configuration options you need or problems you may experience are likely to be solved by reading the included achemso.pdf documentation. The demo template provided here includes the achemso class, bibliography style, documentation and an example template with associated bibliography. For this, they provide a demo template which contains the structure and reference style they would like for submissions.
American Chemical Society (ACS) Publications allows authors to submit their manuscripts formatted in LaTeX to any of their journals.
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